Geometrization of statistical mechanics

Citation
Dc. Brody et Lp. Hughston, Geometrization of statistical mechanics, P ROY SOC A, 455(1985), 1999, pp. 1683-1715
Citations number
44
Categorie Soggetti
Multidisciplinary
Journal title
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES
ISSN journal
13645021 → ACNP
Volume
455
Issue
1985
Year of publication
1999
Pages
1683 - 1715
Database
ISI
SICI code
1364-5021(19990508)455:1985<1683:GOSM>2.0.ZU;2-6
Abstract
Classical and quantum statistical mechanics are cast here in the language o f projective geometry to provide a unified geometrical framework for statis tical physics. After reviewing the Hilbert-space formulation of classical s tatistical thermodynamics, we show that the specification of a canonical po larity on the real projective space RPn induces a Riemannian metric on the state space of statistical mechanics. In the case of the canonical ensemble , equilibrium thermal states are determined by a Hamiltonian gradient how w ith respect to this metric. This flow is characterized by the property that it induces a projective automorphism on the state manifold. The measuremen t problem for thermal systems is studied by the introduction of the concept of a random state. The general methodology is extended to establish a new framework for the quantum-mechanical dynamics of equilibrium thermal states . In this case, the relevant phase space is the complex projective space CP n, here regarded as a real manifold Gamma endowed with the Fubini-Study met ric and a compatible symplectic structure. A distinguishing feature of quan tum thermal dynamics is the inherent multiplicity of thermal trajectories i n the state space, associated with the non-uniqueness of the infinite-tempe rature state. We are then led to formulate a geometric characterization of the standard KMS relation often considered in the context of C* algebras. F inally, we develop a theory of the quantum microcanonical and canonical ens embles, based on the geometry of the quantum phase space Gamma. The example of a quantum spin-1/2 particle in a heat bath is studied in detail.