Re-evaluated gas phase basicity and proton affinity data from the thermokinetic method

Authors
Bouchoux, G Salpin, JY
Citation
G. Bouchoux et Jy. Salpin, Re-evaluated gas phase basicity and proton affinity data from the thermokinetic method, RAP C MASS, 13(10), 1999, pp. 932-936
Citations number
20
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
RAPID COMMUNICATIONS IN MASS SPECTROMETRY
ISSN journal
09514198 → ACNP
Volume
13
Issue
10
Year of publication
1999
Pages
932 - 936
Database
ISI
SICI code
0951-4198(1999)13:10<932:RGPBAP>2.0.ZU;2-Y
Abstract
Gas phase basicity (GB) and proton affinity (PA) determinations by the ther mokinetic method have been reevaluated in the light of the new basicity sca le, It is found that the thermokinetic method provides GB values with a pre cision better than +/-3 kJ/mol, The following GB values are obtained: isobu tene=776.3; acetone=782.1; ketene=790.1; methylketene=809.6; formaldimine=9 29.7; vinylimine=880.3; sulfine = 755.1 kJ/mol, Some discrepancies between the present results and the tabulated values are clarified. Copyright (C) 1 999 John Wiley & Sons, Ltd.