Sb-121,Sb-123 NQR study of solid phases formed in systems (MF)(1-x)-(M ' F)(x)-SbF3-H2O (M, M ' = Na, K, Rb, Cs, and NH4)

Authors
Zemnukhova, LA Davidovich, RL Fedorishcheva, GA
Citation
La. Zemnukhova et al., Sb-121,Sb-123 NQR study of solid phases formed in systems (MF)(1-x)-(M ' F)(x)-SbF3-H2O (M, M ' = Na, K, Rb, Cs, and NH4), RUSS CHEM B, 48(1), 1999, pp. 110-113
Citations number
13
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
1
Year of publication
1999
Pages
110 - 113
Database
ISI
SICI code
1066-5285(199901)48:1<110:SNSOSP>2.0.ZU;2-9
Abstract
Crystalline substances formed in the (MF)(1-x)(M'F)(x)-SbF3-H2O systems (M, M' = Na, K, Rb, Cs, and NH4; x = 0 to 1) were investigated by Sb-121,Sb-12 3 NQR spectroscopy at 77 K. The formation of individual Sb-III complexes Na Cs3Sb4F16 . H2O and NaKSbF5 . 1.5H(2)O, and statistically disordered mixed crystals M1-x-M'(x)-SbF4 (M, M' = K, Rb, Cs, and NH4) was established.