Mass spectra of linear and branched methyl(vinyl)siloxanes

Authors
Voronkov, MG Klyba, LV Basenko, SV Mirskov, RG Bochkarev, VN
Citation
Mg. Voronkov et al., Mass spectra of linear and branched methyl(vinyl)siloxanes, RUSS CHEM B, 48(1), 1999, pp. 114-116
Citations number
6
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
1
Year of publication
1999
Pages
114 - 116
Database
ISI
SICI code
1066-5285(199901)48:1<114:MSOLAB>2.0.ZU;2-W
Abstract
The mass spectra of some linear and branched methyl(vinyl)siloxanes Me3SiOS i(Me)(R)(OSiMeVin)(n)Y (R = Vin, OSiMe3; Y = OSiMe3, Cl; n = 0-2) were stud ied. The regularities of their fragmentation and an anomalously high probab ility of elimination of the ethylene molecule to form the stable 1,3-dioxa- 2,4,6-trisilacyclohexane skeleton were revealed.