Superacidic cyclization of omega-hydroxygeraniol diacetate and omega-hydroxygeraniol benzyl ether acetate

Authors
Kulcitki, V Ungur, N Deleanu, C Vlad, PF
Citation
V. Kulcitki et al., Superacidic cyclization of omega-hydroxygeraniol diacetate and omega-hydroxygeraniol benzyl ether acetate, RUSS CHEM B, 48(1), 1999, pp. 136-138
Citations number
10
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
1
Year of publication
1999
Pages
136 - 138
Database
ISI
SICI code
1066-5285(199901)48:1<136:SCOODA>2.0.ZU;2-K
Abstract
Low-temperature superacidic cyclization of (E,E)-3,7-dimethylocta-2,6-diene -1,8-diol (omega-hydroxygeraniol) diacetate and (E,E)-8-acetoxy-1-benzyloxy -3,7-dimethylocta-2,6-diene leads to the same mixtures of two diastereomeri c 9-acetoxy-8-hydroxy-p-menth-1-enes epimeric at the C(8) atom.