Synthesis and molecular structure of the complex [Ph3Sb(NO3)](2)O center dot Me2CO

Authors
Sharutin, VV Sharutina, OK Panova, LP Nasonova, NV Bliznyuk, TN Belsky, VK
Citation
Vv. Sharutin et al., Synthesis and molecular structure of the complex [Ph3Sb(NO3)](2)O center dot Me2CO, RUSS CHEM B, 48(1), 1999, pp. 173-175
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
1
Year of publication
1999
Pages
173 - 175
Database
ISI
SICI code
1066-5285(199901)48:1<173:SAMSOT>2.0.ZU;2-D
Abstract
The reaction of silver nitrate with Ph3SbBr2 in an ethanol-acetone solution afforded the complex [Ph3Sb(NO3)](2)O . Me2C=O (1). According to the data of X-ray diffraction study of crystals of 1, molecule 1 contains a nonlinea r O-bridge, which links two Sb atoms. The Sb atoms have a trigonal-bipyrami dal configuration. The NO3 group and the bridging oxygen atom are in axial positions and the three Ph substituents are in equatorial positions.