Crystal structure of antimony(III) chloro-fluoro complex K4Sb3F7Cl6

Authors
Udovenko, AA Zemnukhova, LA Gorbunova, YE Mikhailov, YN Davidovich, RL
Citation
Aa. Udovenko et al., Crystal structure of antimony(III) chloro-fluoro complex K4Sb3F7Cl6, RUSS J C CH, 25(5), 1999, pp. 316-319
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
25
Issue
5
Year of publication
1999
Pages
316 - 319
Database
ISI
SICI code
1070-3284(199905)25:5<316:CSOACC>2.0.ZU;2-9
Abstract
Antimony(III) chlor-fluoro complex K4Sb3F7Cl6 Was synthesized and its cryst al structure was determined. The crystals are triclinic, a = 8,626(1), b = 10.804(3), c = 11.284(5) Angstrom, alpha = 67.54(3)degrees, beta = 70.81(3) degrees, gamma = 73.69(3)degrees, V = 903.1(6) Angstrom(3), Z = 2, rho(exp) = 3.21 g/cm(3), rho(calcd) = 3.189 g/cm(3), space group P (1) over bar. Th e structure is built from the isolated anionic [SbF3ClE](-) and [SbFCl4E](2 -) complexes and K+ cations combining the complexes into a three-dimensiona l framework.