Preparation and characterisation of a highly selective surface-ruthenated z
inc oxide sensor for ammonia in trace levels is demonstrated. The introduct
ion of some RuO linkages on the surface of ZnO leads to a dramatic enhancem
ent in the sensitivity (S) to 1000 ppm level of ammonia at 300 degrees C (S
= 440) as compared to the similar response obtained for pure ZnO (S = 1.5)
. A systematic study using various characterisation techniques such as EDAX
, SEM, CV and XPS indicates the key role played by the amount and distribut
ion of Ru species on the surface. (C) 1999 Elsevier Science S.A. All rights
reserved.