Molecular thermodynamic model for reverse micelles system and protein extraction - I. Molecular thermodynamic model for reverse micelles system

Authors
Citation
Sq. Zhou et Sy. Guo, Molecular thermodynamic model for reverse micelles system and protein extraction - I. Molecular thermodynamic model for reverse micelles system, ACT CHIM S, 57(5), 1999, pp. 437-445
Citations number
22
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
57
Issue
5
Year of publication
1999
Pages
437 - 445
Database
ISI
SICI code
0567-7351(1999)57:5<437:MTMFRM>2.0.ZU;2-A
Abstract
A thermodynamic molecular model is presented by analyzing three effects rel ated to the formation of reverse micelles system comprehensively i.e. low i nterfacial tension effect,interfacial bending effect,mixing entropy effect, based on thermodynamic analysis on the stability of reverse micelles system . The predicted changes in water content of reverse micelles system with th e variation of inorganic salt type and concentration, surfactant concentrat ion and consurfactant content are in accordance with the experimental law o btained quantitatively. The model can also predict electrostatic potential value on the inside surface of the reverse micelles system and surfactant d issociation degree.