A new series of dyes for nonlinear optical (NLO) and photorefractive (PR) a
pplications investigated by optical and electrooptical absorption spectrosc
opy. Optimized PR and NLO chromophores are obtained based on the exceptiona
lly strong heterocyclic thiazolidenemalononitrile acceptor unit, combined w
ith the proper choice of electron donor unit and conjugation length.