MU-OXO DIFERRIC COMPLEXES AS OXIDATION CATALYSTS WITH HYDROGEN-PEROXIDE AND THEIR POTENTIAL IN ASYMMETRIC OXIDATION

Authors
DUBOCTOIA C MENAGE S LAMBEAUX C FONTECAVE M
Citation
C. Duboctoia et al., MU-OXO DIFERRIC COMPLEXES AS OXIDATION CATALYSTS WITH HYDROGEN-PEROXIDE AND THEIR POTENTIAL IN ASYMMETRIC OXIDATION, Tetrahedron letters, 38(21), 1997, pp. 3727-3730
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
21
Year of publication
1997
Pages
3727 - 3730
Database
ISI
SICI code
0040-4039(1997)38:21<3727:MDCAOC>2.0.ZU;2-G
Abstract
Non-heme diiron complexes, as models of methane monooxygenase, provide a new class of catalysts for oxidation reactions. We show here that s uch complexes have the potential for catalyzing stereoselective oxidat ions of sulfides by hydrogen peroxide. (C) 1997 Elsevier Science Ltd.