A. Martin et al., Catalytic performance of vanadyl pyrophosphate in the partial oxidation oftoluene to benzaldehyde, CATAL LETT, 59(1), 1999, pp. 61-65
Vanadyl pyrophosphate catalysts were generated by dehydrating VOHPO4.(1/2)H
2O at different temperatures and duration of the dehydration procedure. The
as-synthesised materials were characterised by X-ray diffractometry, FTIR
spectroscopy and temperature-programmed reduction. The prolongation of the
formation period at higher temperatures led to improved crystallinity and l
ower BET surface areas of the vanadyl pyrophosphate specimens and, addition
ally, a significantly impeded reducibility of the vanadyl sites was observe
d. The catalytic performance of the samples was tested in the partial oxida
tion of toluene to benzaldehyde. The obtained results revealed an increasin
g benzaldehyde selectivity with improved catalyst crystallinity. In situ FT
IR and ESR spectroscopy were used to throw more light on the interaction of
the toluene-air feed with the surface of the catalyst.