Unusual cyclopropanol formation from a beta-silyl aldehyde

Authors
Fleming, I Mandal, AK
Citation
I. Fleming et Ak. Mandal, Unusual cyclopropanol formation from a beta-silyl aldehyde, CHEM COMMUN, (10), 1999, pp. 923-924
Citations number
82
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
10
Year of publication
1999
Pages
923 - 924
Database
ISI
SICI code
1359-7345(19990521):10<923:UCFFAB>2.0.ZU;2-9
Abstract
The hemiacetals 15 and 18 gave cyclopropanols 17 and 20 when treated with N aH in DMSO, showing that the silyl group has enhanced electrofugal powers b ecause of the participation of the oxyanion.