QUANTITATIVE-ANALYSES OF CIEPLAK VS FELKIN-ANH EFFECTS IN HYDRIDE REDUCTION OF CYCLOHEXANONE

Authors
SENJU T TOMODA S
Citation
T. Senju et S. Tomoda, QUANTITATIVE-ANALYSES OF CIEPLAK VS FELKIN-ANH EFFECTS IN HYDRIDE REDUCTION OF CYCLOHEXANONE, Chemistry Letters, (5), 1997, pp. 431-432
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
5
Year of publication
1997
Pages
431 - 432
Database
ISI
SICI code
0366-7022(1997):5<431:QOCVFE>2.0.ZU;2-#
Abstract
Transition structures of LIH addition to cyclohexanone have been optim ized at the B3LYP/6-31G level. The bond lengths of the incipient bond become substantially elongated compared to the previous results at th e HF/3-21G level. It has been revealed that both torsional effects and hyperconjugative stabilization are of less importance for the pi-faci al diastereoselectivity.