Research topics and methods of green chemistry in chromate production are i
ntroduced in this paper. New original green chemical process of the heterog
eneous reaction and separation system of liquid phase oxidation of chromite
in molten salt of sodium hydroxide-one way separation in high concentratio
n medium-metastable phase separation-carbonate recycle conversion has been
developed. The green commercial process for comprehensive utilization of mi
neral resources-reactant recycle inside the process-zero emission was estab
lished.