HPLC resolution of the enantiomers of glycidyl sulfides and glycidyl selenides on amylose tris-(phenylcarbamate) stationary phase

Authors
Yu, ZW Zhou, ZQ Liu, YQ Jiang, SX Chen, LR
Citation
Zw. Yu et al., HPLC resolution of the enantiomers of glycidyl sulfides and glycidyl selenides on amylose tris-(phenylcarbamate) stationary phase, CHROMATOGR, 49(9-10), 1999, pp. 572-574
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
CHROMATOGRAPHIA
ISSN journal
00095893 → ACNP
Volume
49
Issue
9-10
Year of publication
1999
Pages
572 - 574
Database
ISI
SICI code
0009-5893(199905)49:9-10<572:HROTEO>2.0.ZU;2-H
Abstract
The resolution of the enantiomers of a series of glycidyl sulfides and glyc idyl selenides has been examined on a chiral stationary phase prepared by c oating aminopropylated silica gel with amylose tris-(phenylcarbamate). Most of the enantiomers of glycidyl monosulfides and monoselenides could be res olved satisfactorily but those of the disulfides could nor. The effects of solute structure and of the concentration of 2-propanol in the mobile phase on retention and resolution were investigated.