S-triazine herbicides are widely used for preemergence and postemergence we
ed control. In order to understand the behaviour of s-triazines herbicides
in soil, it is necessary to know the processes which govern the persistence
and the transformation of this compounds in water, soil and air. Photochem
ical investigations in aqueous solution constitute a considerable interest
for the mineralization, transformation and the elimination of pesticides in
different environmental compartments. Under simulated solar light (lambda
greater than or equal to 290nm), the half life of terbuthylazine in distill
ed water with and without humic substances are 8.01 hours and 23.1 hours re
spectively with a first order kinetic. In soil and in aqueous solution at l
ambda greater than or equal to 290nm, dealkylation is the most important pa
thway of degradation of terbuthylazine, the conversion products are desethy
lterbuthylazine and desisobutylterbuthylazine.