The polymerization of a humic acid (HA) from a volcanic soil under a Medite
rranean oak forest, when exposed to an oxidative. enzyme such as a peroxida
se from horseradish was investigated. The polymerization of the HA increase
d in the presence of the enzyme in respect to the control solution. The deg
ree of HA polymerization was evaluated by High Pressure Size Exclusion Crom
atography (HPSEC) and by using a disaggregation technique based on acetic a
cid addition to the HA.