New anellation reactions of pyranose derivatives

Citation
K. Methling et al., New anellation reactions of pyranose derivatives, J CARB CHEM, 18(4), 1999, pp. 429-439
Citations number
24
Categorie Soggetti
Chemistry & Analysis
Journal title
JOURNAL OF CARBOHYDRATE CHEMISTRY
ISSN journal
07328303 → ACNP
Volume
18
Issue
4
Year of publication
1999
Pages
429 - 439
Database
ISI
SICI code
0732-8303(1999)18:4<429:NAROPD>2.0.ZU;2-O
Abstract
The push-pull-activated pyranosidulose 2 reacted with acetylacetone and met hyl acetoacetate to afford the anellated pyranosides 3 and 4, respectively. Treatment of the ulose 2 with acetoacetamide and malononitrile, respective ly, furnished the fused pyridones 5 and 6. Benzo-anellated pyranosides 7 we re obtained by reaction of pyranosidulose 2 with dialkyl 3-oxoglutarates.