The vapor-liquid equilibrium (VLE) isotherms were directly determined by th
e ebulliometric method for the system 2-ethoxyethanol + methanol. The exper
imental results were correlated by an equation of state that is capable of
reproducing VLE for associating and reacting systems with an accuracy simil
ar to the experiment uncertainty over a reasonable range of pressure and te
mperature. Such correlations are hard to obtain with equations representing
activity coefficients at specific particular isotherms.