Excess volumes, relative permittivity increments, and excess molar polarizations of {xCH(2)CCH(3)CO(2)CH(3)+(1-x)(C6H6, or C7H8, or o-C8H10, or m-C8H10, or p-C8H10, or C8H10, or c-C6H12)}

Citation
Nv. Sastry et al., Excess volumes, relative permittivity increments, and excess molar polarizations of {xCH(2)CCH(3)CO(2)CH(3)+(1-x)(C6H6, or C7H8, or o-C8H10, or m-C8H10, or p-C8H10, or C8H10, or c-C6H12)}, J CHEM THER, 31(6), 1999, pp. 797-809
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL THERMODYNAMICS
ISSN journal
00219614 → ACNP
Volume
31
Issue
6
Year of publication
1999
Pages
797 - 809
Database
ISI
SICI code
0021-9614(199906)31:6<797:EVRPIA>2.0.ZU;2-V
Abstract
The excess molar volumes V-m(E), relative permittivity increments delta eps ilon(r), and excess molar polarization P-m(E) of {xCH(2)CCH(3)CO(2)CH(3) (1 - x)(C6H6, or C7H8, or o-C8H10, or m-C8H10, or p-C8H10, or C8H10, or c-C 6H12)} have been measured at the temperatures 298.15 K and 308.15 K. The re sults for V-m(E), delta epsilon(r), and P-m(E) indicate that structure-disr uptive interactions between the acrylic ester and hydrocarbons predominate over the specific interactions and contribute to the sign and magnitude of the individual excess functions. (C) 1999 Academic Press.