Zp. Li et al., The nature of colloid and interface of miscible phase system in alkaline-surfactant combination flooding, J DISP SCI, 20(4), 1999, pp. 1143-1162
Several representative systems of surfactant + alkaline combination floodin
g are chosen to study in this paper, these systems are characterized in two
points: The first: oil is miscible with water only by reversing them five
to ten times, this miscible process is close to spontaneous. Interfacial te
nsion between oil and aqueous is ultra-low. The second: this type of system
s is high dispersion and can be stabilized in a period of time. These syste
ms are observed by microscopy, polarizing microscopy, microcalorimetry, las
er particles analysis instrument and interfacial tension meter, it is found
that small particles are main constituent and special liquid crystals dist
ributed on the surface of small particles exist. Small particles and specia
l liquid crystals are responsible for producing ultra-low interfacial tensi
on. The middle phase microemulsion of sodium dodecylsulfate is studied. By
comparing difference and similarity between middle phase microemulsion and
miscible system, mechanisms of forming low interfacial tension in miscible
system and middle phase microemulsion are discussed initially.