SYNTHESIS AND CHARACTERIZATION OF METHYLPALLADIUM(II) DITHIOLATE COMPLEXES OF THE TYPE [PDME(S-S)(ER3)] (S-S=S2CNR2, S2COET, S2P(OR)(2), S2PPH2, ER3=PMEPH2, PPH3, ASPH3)

Authors
NARAYAN S JAIN VK CHAUDHURY S
Citation
S. Narayan et al., SYNTHESIS AND CHARACTERIZATION OF METHYLPALLADIUM(II) DITHIOLATE COMPLEXES OF THE TYPE [PDME(S-S)(ER3)] (S-S=S2CNR2, S2COET, S2P(OR)(2), S2PPH2, ER3=PMEPH2, PPH3, ASPH3), Journal of organometallic chemistry, 530(1-2), 1997, pp. 101-104
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
530
Issue
1-2
Year of publication
1997
Pages
101 - 104
Database
ISI
SICI code
0022-328X(1997)530:1-2<101:SACOMD>2.0.ZU;2-B
Abstract
Methylpalladium(II) dithiolate complexes of the type [PdMe(S ( ) over cap S)(ER3)] (S ( ) over cap S = S2CNR2 (R = Me or Et), S2COEt, S2P(OR )(2) (R = Et, Pr-n, Pr-1), S2PPh2; ER3 = PMePh2, PPh3, AsPh3) have bee n synthesized by the reaction of [Pd2Me2(mu-Cl)(2)(PMePh2)(2)] with so dium/potassium/ammonium salts of the dithio acid or by treatment of [P dMeCl(cod)] with ER3 followed by sodium/potassium/ammonium salts of th e dithio ligand. All the complexes were characterized by elemental ana lysis, LR and nuclear magnetic resonance (H-1, (31)p) data.