Vibrational spectroscopic investigations of M(imidazole)(2)Ni(CN)(4)centerdot 2 dioxane clathrates

Authors
Tufan, Y Karacan, N Davies, JED
Citation
Y. Tufan et al., Vibrational spectroscopic investigations of M(imidazole)(2)Ni(CN)(4)centerdot 2 dioxane clathrates, J INCL P MA, 33(2), 1999, pp. 149-154
Citations number
17
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
ISSN journal
13883127 → ACNP
Volume
33
Issue
2
Year of publication
1999
Pages
149 - 154
Database
ISI
SICI code
1388-3127(199902)33:2<149:VSIOM>2.0.ZU;2-K
Abstract
Four new clathrates of the formula M(lm)(2)Ni(CN)(4). 2 . Dioxane (where M = Co, Ni, Cu, Cd; Im = Imidazole) have been prepared in powder form and the ir FT-IR and laser-Raman spectra are reported for the first time. These cla thrates are analogues to the previously reported classical Hofmann type cla thrates except for the copper clathrate. The Cu clathrate has different spe ctral features in comparison with its analogues due to the Jahn-Teller effe ct.