C. Vahlas et al., Low pressure chemical vapor deposition from TEOS-NH3 mixtures: thermochemical study of the process considering kinetic data, MICROEL REL, 39(2), 1999, pp. 303-309
A calculational thermodynamic investigation of the chemical vapor depositio
n (CVD) of SiO2 films from TEOS/NH3 mixtures has been performed, by minimiz
ing the Gibbs energy of the C-H-N-O-Si chemical system. Calculations are ba
sed on an upgraded thermodynamic data bank which includes silicon containin
g complex gaseous compounds. The obtained results illustrate the influence
of temperature, of pressure, and of initial gas composition on the formatio
n of stable phases. Partial equilibrium calculations were also performed, i
n order to investigate the predominant mechanisms for deposition. These cal
culations have been conducted (a) by excluding the solid phases from the ca
lculations, and (b) by assuming a partial striping and elimination of the e
thoxy ligands in the gas phase before reaching the growing surface. Finally
, the supersaturation of the gas phase relative to silicon dioxide and the
corresponding driving force for the deposition have been evaluated in diffe
rent processing conditions. A direct relation between driving force and the
growth rate of the deposits has thus been evidenced.
The aim of this research is to contribute to the definition of optimum cond
itions for the processing of materials which can be used as dielectrics in
integrated circuits, and as waveguides in optoelectronics. (C) 1999 Elsevie
r Science Ltd. All rights reserved.