Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex

Authors
Kakiuchi, F Yamada, A Chatani, N Murai, S Furukawa, N Seki, Y
Citation
F. Kakiuchi et al., Silyl group transfer from allylsilanes to olefins catalyzed by a ruthenium(II) complex, ORGANOMETAL, 18(10), 1999, pp. 2033-2036
Citations number
72
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
10
Year of publication
1999
Pages
2033 - 2036
Database
ISI
SICI code
0276-7333(19990510)18:10<2033:SGTFAT>2.0.ZU;2-9
Abstract
Dehydrogenative silylation of olefins, such as styrenes, methyl acrylate, a nd vinyl ether, using allyltriethoxysilane as the source of the silyl group can be catalyzed by RuHCl(CO)(PPh3)(3) to give the corresponding vinylsila nes in good to excellent yields. The ruthenium complex also catalyzed the s elf-dehydrogenative silylation of allylsilanes, yielding 1,3-bis(triorganos ilyl)propenes.