A structure-activity relationship (SAR) for predicting rate constants for the reaction of NO3, OH and O-3 with monoalkenes and conjugated dienes

Authors
King, MD Canosa-Mas, CE Wayne, RP
Citation
Md. King et al., A structure-activity relationship (SAR) for predicting rate constants for the reaction of NO3, OH and O-3 with monoalkenes and conjugated dienes, PCCP PHYS C, 1(9), 1999, pp. 2239-2246
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PCCP PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
1
Issue
9
Year of publication
1999
Pages
2239 - 2246
Database
ISI
SICI code
1463-9076(19990501)1:9<2239:ASR(FP>2.0.ZU;2-3
Abstract
A simple method of predicting rate constants for the reaction between NO3, OH or O-3 and substituted alkenes (monoalkenes and conjugated dienes) has b een demonstrated using a simple structure-activity relationship (SAR) based on the structure of the alkene. The SAR is useful in providing an initial estimate of an unknown rate constant for a reaction of an alkene and the im portant tropospheric oxidants NO3, OH or O-3.