Multi-step photolysis of benzenetetracarboxylic dianhydrides in low-temperature argon matrices: exploration of reactive intermediates containing benzdiynes produced stepwise during photochemical reactions

Photolyses of 1,2;4,5- and 1,2;3,4-benzenetetracarboxylic dianhydrides (3a and 3b), which would be precursors of 1,4- and 1,3-benzdiyne (2a and 2b), w ere studied by a matrix isolation technique and a selective irradiation tec hnique using three kinds of excimer lasers in order to directly observe int ermediates produced stepwise. The photolyzed products in the matrix were ch aracterized by FT-IR and W-vis spectroscopies. As a result, sequential deca rboxylation and decarbonylation from one anhydride moiety of 3a and 3b prod uced corresponding benzocyclopropenone and benzyne intermediates in the ini tial stage. In both the photolyses, further decomposition proceeded to form 1,3,5-hexatriyne (4) as a final product. Although neither 2a nor 2b was ob served directly, it seems that the benzdiynes including another isomer, 1,2 ,3,5-tetradehydrobenzene (2c), participated as precursors to acyclic C4H-C= C-H biradical 13 and/or carbene 14, which were formed in the reaction from benzdiyne to 4. Additionally, as a result of CCSD(T)/6-31G**//CASSCF(4,4)/6 -31G** level calculations for 2a, 2b and 2c, it is clear that the energy of 2c was comparable to those of 2a and 2b, which supports the formation of 1 3 from 2a/2b and of 14 from 2c after isomerization of 2a --> 2c and 2b --> 2c.