Specular neutron reflection is used to depth profile noninvasively water in
corporation into float glass surfaces as a function of immersion time. The
effective nanometre resolution of the technique, allied with the contrast v
ariation method, has uniquely revealed the presence of two layers containin
g water. The first layer occurs at the glass surface and has a thickness th
at remains constant at 30 Angstrom under conditions of 100% relative humidi
ty. The second layer penetrates ever deeper into the glass as the time of i
mmersion lengthens, and is accompanied by a loss of material from the glass
itself.