The experimental and theoretical progress in understanding the electronic s
tructure and the related parameters of Schottky interfaces and heterojuncti
ons is reviewed. Particular emphasis is devoted to the solution of several
historical controversial points, to the impact of novel ab initio theoretic
al approaches, to new experimental techniques based on synchrotron light an
d free electron lasers, to the efforts towards controlled modifications of
interface parameters and to the foreseeable future developments of this vig
orously progressing and:technologically crucial field.