Rheology of polymer blends: linear model for viscoelastic emulsions

Authors
Citation
M. Bousmina, Rheology of polymer blends: linear model for viscoelastic emulsions, RHEOL ACT, 38(1), 1999, pp. 73-83
Citations number
22
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
RHEOLOGICA ACTA
ISSN journal
00354511 → ACNP
Volume
38
Issue
1
Year of publication
1999
Pages
73 - 83
Database
ISI
SICI code
0035-4511(199905)38:1<73:ROPBLM>2.0.ZU;2-8
Abstract
Kerner's model for flow of composite elastic media is extended to an emulsi on of viscoelastic phases with interfacial tension undergoing deformations of small amplitude. A privileged internal structure inside the suspended dr ops is discussed in terms of fluid circulation across the interface. It is shown that for usual drop radius and interfacial tension values of emulsion s, the rheological behavior predicted by the model, with very simple expres sion for the complex shear modulus, is quantitatively similar to that predi cted by Palierne's model. Predictions of the model are compared with experi mental data obtained on a polystyrene/polyethylene blend sheared in a small -amplitude oscillatory mode.