Effect of reaction of MoCl5 with atmospheric water on its intercalation into graphite

Authors
Mittal, J Inagaki, M
Citation
J. Mittal et M. Inagaki, Effect of reaction of MoCl5 with atmospheric water on its intercalation into graphite, SOL ST ION, 121(1-4), 1999, pp. 183-188
Citations number
26
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE IONICS
ISSN journal
01672738 → ACNP
Volume
121
Issue
1-4
Year of publication
1999
Pages
183 - 188
Database
ISI
SICI code
0167-2738(199906)121:1-4<183:EOROMW>2.0.ZU;2-3
Abstract
The presence of MoOCl3 with MoCl5 was found to change the stage structure o f resultant graphite intercalation compounds (GICs) with MoCl5. Heating MoO Cl3 with MoCl5 and graphite at 200 degrees C for seven days produced stage- 1 MoCl5-GIC in a single phase, though no addition of MoOCl3 resulted in the formation of poorly crystallized stage-3 GIC and a large amount of its add ition in no intercalation of MoCl5. (C) 1999 Elsevier Science B.V. All righ ts reserved.