A novel synthesis of 4,6-dimethyl-2-pyrone from carbon dioxide and mesityloxide in the presence of an ethylzinc carbamate

Authors
Zhou, M Yoshida, Y Ishii, S Noguchi, H
Citation
M. Zhou et al., A novel synthesis of 4,6-dimethyl-2-pyrone from carbon dioxide and mesityloxide in the presence of an ethylzinc carbamate, SYN COMMUN, 29(13), 1999, pp. 2241-2247
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
13
Year of publication
1999
Pages
2241 - 2247
Database
ISI
SICI code
0039-7911(1999)29:13<2241:ANSO4F>2.0.ZU;2-V
Abstract
The title synthesis, the first example of the CO2 fixation by use of an alp ha,beta-unsaturated ketone, has been successfully carried out, most prefera bly in triethylamine or pyridine at 120-160 degrees C in the presence of et hylzinc diphenylcarbamate.