Citation
A. Srinivasan et al., Novel heteroatom containing rubyrins, TETRAHEDRON, 55(21), 1999, pp. 6671-6680
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020
→ ACNP
Volume
55
Issue
21
Year of publication
1999
Pages
6671 - 6680
Database
ISI
SICI code
0040-4020(19990521)55:21<6671:NHCR>2.0.ZU;2-F
Abstract
Synthesis of rubyrins containing two or three heteroatoms (O, S, Se) in the
core is accomplished using modified diols and tetrapyrromethanes. Substitu
tion of heteroatoms leads to significant reductions in HOMO-LUMO gap and ea
sier oxidations and reductions reflecting the changes in electronic structu
re of the rubyrin skeleton. (C) 1999 Elsevier Science Ltd. All rights reser
ved.