Ceric(IV) ammonium nitrate in the selective conversion of hydrazides to esters

Citation
B. Stefane et al., Ceric(IV) ammonium nitrate in the selective conversion of hydrazides to esters, TETRAHEDR L, 40(23), 1999, pp. 4429-4432
Citations number
23
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
23
Year of publication
1999
Pages
4429 - 4432
Database
ISI
SICI code
0040-4039(19990604)40:23<4429:CANITS>2.0.ZU;2-J
Abstract
Hydrazides were treated with ceric(IV) ammonium nitrate (CAN) in the presen ce of the appropriate alcohol as a nucleophile to afford esters in good yie lds. Reactions took place exclusively at the hydrazino moiety even when oth er sensitive groups were present in either of the partners. (C) 1999 Elsevi er Science Ltd, All rights reserved.