A versatile and efficient approach to enantiomerically pure monodentate and bidentate P-chiral phosphines

Authors
Leung, PH Liu, AM Mok, KF
Citation
Ph. Leung et al., A versatile and efficient approach to enantiomerically pure monodentate and bidentate P-chiral phosphines, TETRAHEDR-A, 10(7), 1999, pp. 1309-1314
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
7
Year of publication
1999
Pages
1309 - 1314
Database
ISI
SICI code
0957-4166(19990409)10:7<1309:AVAEAT>2.0.ZU;2-L
Abstract
Enantiomerically pure (R)-methylphenylvinylphosphine and the P-chiral dipho sphine ligands (5R,7R)-, (5R,7S)- and (SS,7R)-[5-(methylphenylphosphino)-2, 3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene] were stereospecifica lly obtained in high yields from the chiral palladium template controlled D iels-Alder reaction between (+/-)-methylphenylphosphine and 3,4-dimethylphe nylphosphole. (C) 1999 Elsevier Science Ltd. All rights reserved.