Chiral pyridylmethyl- and quinolinyl-oxazolines as ligands for enantioselective palladium-catalyzed allylic alkylation

Authors
Chelucci, G Gladiali, S Saba, A
Citation
G. Chelucci et al., Chiral pyridylmethyl- and quinolinyl-oxazolines as ligands for enantioselective palladium-catalyzed allylic alkylation, TETRAHEDR-A, 10(7), 1999, pp. 1393-1400
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
7
Year of publication
1999
Pages
1393 - 1400
Database
ISI
SICI code
0957-4166(19990409)10:7<1393:CPAQAL>2.0.ZU;2-4
Abstract
Chiral pyridylmethyl- and quinolinyl-oxazolines were prepared and assessed in the enantioselective palladium-catalyzed allylic substitution of 1,3-dip henylprop-2-enylacetate with dimethyl malonate. Enantioselectivities up to 77% were obtained. (C) 1999 Elsevier Science Ltd. All rights reserved.