Jx. Zhang et al., The growth mechanism of the coloured passive film formed on 304 stainless steel in sulfuric solution without Cr6+ ion by using AV passivation, T I MET FIN, 77, 1999, pp. 106-107
A thick passive film showing interference colours has been obtained on 304
stainless steel in sulfuric acid solution without Cr6+ ions by applying alt
ernating square wave polarization. An investigation of the chemical composi
tion and the distribution of valence states in the profile of the film has
been carried out by using XPS. A mechanism for the colouring process is pro
posed.