Metallic complexes from 2-furaldehyde semicarbazone and 5-methyl-(2-furaldehyde) semicarbazone

Authors
Ibrahim, G Chebli, E Khan, MA Bouet, GM
Citation
G. Ibrahim et al., Metallic complexes from 2-furaldehyde semicarbazone and 5-methyl-(2-furaldehyde) semicarbazone, TRANSIT MET, 24(3), 1999, pp. 294-298
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
3
Year of publication
1999
Pages
294 - 298
Database
ISI
SICI code
0340-4285(199906)24:3<294:MCF2SA>2.0.ZU;2-3
Abstract
The synthesis and characterization of Co-II, Ni-II, Cu-II and Cd-II complex es with 2-furfuralsemicarbazone (FSC) and 5-methyl 2-furfuralsemicarbazone (MFSC) are reported. These ligands lead to the complexes: [ML2X2] or [MLX2] (L = FSC or MFSC) whose structures were determined using elemental analysi s, molar conductivity, magnetic measurements, i.r., far i.r. and electronic spectra as well as by n.m.r. FSC and MFSC act as bidentate ligands in most of the Co-II, Ni-II, Cu-II and Cd-II complexes. MFSC is a monodentate liga nd in [NiBr2(MFSC)(4)].