X-ray crystal structure of [VO(DPA)(H2O)(2)]center dot 2H(2)O (DPA = dipicolinate dianion)

Authors
Chatterjee, M Ghosh, S Nandi, AK
Citation
M. Chatterjee et al., X-ray crystal structure of [VO(DPA)(H2O)(2)]center dot 2H(2)O (DPA = dipicolinate dianion), TRANSIT MET, 24(2), 1999, pp. 183-185
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
2
Year of publication
1999
Pages
183 - 185
Database
ISI
SICI code
0340-4285(199904)24:2<183:XCSO[D>2.0.ZU;2-I
Abstract
The X-ray crystal structure of the trans-diaqua complex [VO(DPA)(H2O2)]. 2H (2)O (I) (DPA = dipicolinate dianion) has been determined. Comparison with the known structure of [VO(DPA)(o-phen)]. 3H(2)O (2), obtained from (1) by displacement of the two coordinated aqua molecules, shows that the coordina tion sphere around vanadium is reorganised during this reaction.