The chemistry of pyridinethiols and related ligands, Part 9. Synthesis, spectroscopy and crystal structure of sulphur bridged dimeric [{eta(3)-(O-mu-S)-1-oxopyridine-2-thione}(triphenylphosphine)silver(I)]

Authors
Lobana, TS Paul, S Hundal, G Obrai, S
Citation
Ts. Lobana et al., The chemistry of pyridinethiols and related ligands, Part 9. Synthesis, spectroscopy and crystal structure of sulphur bridged dimeric [{eta(3)-(O-mu-S)-1-oxopyridine-2-thione}(triphenylphosphine)silver(I)], TRANSIT MET, 24(2), 1999, pp. 202-205
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
2
Year of publication
1999
Pages
202 - 205
Database
ISI
SICI code
0340-4285(199904)24:2<202:TCOPAR>2.0.ZU;2-W
Abstract
Reaction of 1-hydroxypyridine-2-thione (HpyOS) in CHCl3 with Ag2CO3 suspend ed in CHCl3 under magnetic stirring followed by addition of PPh3 yields a p roduct of stoichiometry: Ag(pyOS)(PPh3). The compound adopts a dimeric stru cture [Ag(pyOS)(PPh3)](2) (1) where each Ag atom acquires a distorted tetra hedral geometry by co-ordinating to one oxygen, two sulphur and one phospho rus atoms. The Ag2S2 core forms a parallelogram [Ag-S 2.507(1), 2.822(1)Ang strom] with Ag-S-Ag and S-Ag-S angles of 74.8(1) and 105.2(1)degrees, respe ctively.