X-band e.p.r. spectra of imidazole imidazolate bridged polynuclear copper(II) complexes

Authors
Patel, RN Pandey, HC Pandeya, KB
Citation
Rn. Patel et al., X-band e.p.r. spectra of imidazole imidazolate bridged polynuclear copper(II) complexes, TRANSIT MET, 24(1), 1999, pp. 35-37
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
1
Year of publication
1999
Pages
35 - 37
Database
ISI
SICI code
0340-4285(199902)24:1<35:XESOII>2.0.ZU;2-K
Abstract
X-band e.p.r. spectra of polycrystalline, polynuclear complexes of the type [(dien)Cu-im-Cu(dien)](n)(ClO4)(n) and [(dien)Cu-imH-Cu(dien)](n)(ClO4)(2n ) are described, where dien = diethylenetriamine, imH and im are imidazole (and 2-methyl- and 2-ethylimidazole) respectively. All the complexes show e .p.r. spectra characteristic of S = 1, which yield the value of the zero fi eld splitting parameter, D, in the 0.030 +/- 0.001 cm(-1) range.