Sulfur oxychloride-organic hydroperoxide initiating systems in the homo- and copolymerization of methacrylic monomers

Authors
Lelekov, VE Aleksandrov, YA Biryukova, TG
Citation
Ve. Lelekov et al., Sulfur oxychloride-organic hydroperoxide initiating systems in the homo- and copolymerization of methacrylic monomers, VYSO SOED, 41(4), 1999, pp. 715-717
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B
ISSN journal
05075475 → ACNP
Volume
41
Issue
4
Year of publication
1999
Pages
715 - 717
Database
ISI
SICI code
0507-5475(199904)41:4<715:SOHISI>2.0.ZU;2-U
Abstract
The kinetics of bulk polymerization of methyl methacrylate and of its copol ymerization with styrene initiated by sulfur oxychloride-organic hydroperox ide systems was studied. The kinetic and activation parameters of the polym erization process and the stage of initiation were determined. It was estab lished that initiation proceeds with participation of the chloride-hydroxyp eroxide complex (1 : 1), which is responsible for the generation of radical s initiating polymerization.