Bis[N-benzoyl-N '-(2-pyridylmethylene)-hydrazine]trinitratocerium(III) acetone dihydrate

Authors
Christidis, PC Tossidis, IA Paschalidis, DG
Citation
Pc. Christidis et al., Bis[N-benzoyl-N '-(2-pyridylmethylene)-hydrazine]trinitratocerium(III) acetone dihydrate, ACT CRYST C, 55, 1999, pp. 707-710
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
5
Pages
707 - 710
Database
ISI
SICI code
0108-2701(19990515)55:<707:B'A>2.0.ZU;2-M
Abstract
The crystal structure of the title compound, [Ce(NO3)(3)(C13H11N3O)(2)] . C 3H6O.2H(2)O, has been determined. The Ce-III atom is 12-coordinate by linki ng to two tridentate 2-pyridinecarboxaldehyde benzoylhydrazone ligands and three bidentate nitrate ligands. The Ce-O distances range between 2.528 (3) and 2.759(4) Angstrom, and the Ce-N distances range between 2.725(4) and 2 .848(4) Angstrom. All the water molecules are involved in hydrogen-bond for mation with the Ce-containing molecules.