A chain of fused R-2(2)(10) and R-6(4)(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

Authors
Ferguson, G Gregson, RM Glidewell, C
Citation
G. Ferguson et al., A chain of fused R-2(2)(10) and R-6(4)(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2), ACT CRYST C, 55, 1999, pp. 815-817
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
5
Pages
815 - 817
Database
ISI
SICI code
0108-2701(19990515)55:<815:ACOFRA>2.0.ZU;2-K
Abstract
The title compound is a salt, i.e. 4,11-diaza-1,8-diazoniacyclotetradecane bis[2(2-hydroxyphenyl)phenolate], C10H26N42+.2HOC(6)H(4)C(6)H(4)O(-). The c entrosymmetric cation contains two intramolecular N-H...N hydrogen bonds, w ith an N...N distance of 2.865 (2) Angstrom, and the anion contains an intr amolecular O-H...O hydrogen bond, with an O...O distance of 2.486 (2) Angst rom. The ions are linked into continuous chains by means of two types of N- H...O hydrogen bond having N...O distances of 2.682(2) and 3.273 (2) Angstr om.