This paper is devoted to the numerical approximation of the discontinuous s
olutions of the Euler equations for weakly ionized mixtures of reacting gas
es. The main difficulty stems from the non conservative formulation of thes
e equations due to a widely used physical assumption. We show how to derive
a well-posed conservative reformulation of the equations from the analysis
of the associated full convective-diffusive system. We then propose an exa
ct Roe-type linearization for the equivalent system of conservation laws on
the basis of an original Lemma for averagings. Our results can be seen as
an extension of the classical Roe average, for nonlinearities that cannot b
e recast under quadratic form.