The prime tasks of cementing an oil well are to keep the casing in place, t
o prevent corrosion from formation water, and, most importantly, to avoid t
he flow of fluids on the outside of the casing. Sometimes gas migration in
cement slurries occurs when gas present in the formation exerts pressure ag
ainst the cement slurry column, causing the formation of microfractures in
the setting matrix, expecially during the transition time of the slurry. Ma
ny studies have been conducted in the last two decades to help in understan
ding which properties the cement slurry must have to avoid the migration of
such fluids. In this paper we propose a new rheological approach to evalua
te the capacity of a cement slurry to stop the migration of fluids from the
formation in the wells where the risk of gas migration is relatively high,
especially during the transition time. Our rheological approach is based o
n small amplitude oscillatory measurements. We collected information on eit
her kinetics of gelation of cements for oil well usage or the strength of t
heir structures. This fundamental approach has been useful to formulate dif
ferent cement slurries that have been used with success in several field tr
ials where the risk of gas migration was relatively high. (C) 1999 Elsevier
Science Ltd. All rights reserved.