Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under exceedingly mild conditions - a novel possibility of carbon dioxide activation

Authors
Joo, F Laurenczy, G Nadasdi, L Elek, J
Citation
F. Joo et al., Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under exceedingly mild conditions - a novel possibility of carbon dioxide activation, CHEM COMMUN, (11), 1999, pp. 971-972
Citations number
21
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
1999
Pages
971 - 972
Database
ISI
SICI code
1359-7345(19990607):11<971:HHOAHC>2.0.ZU;2-P
Abstract
Water soluble ruthenium(II)- and rhodium(I)-phosphine complexes catalyze th e hydrogenation of aqueous HCO3 - to HCO2- under mild conditions with turno ver frequencies up to 262 TO h(-1).