Metal-oxo cluster-supported transition metal complexes: hydrothermal synthesis and characterization of [{M(phen)(2)}(2)(Mo8O26)] (M = Ni or Co)

Authors
Xu, JQ Wang, RZ Yang, GY Xing, YH Li, DM Bu, WM Ye, L Fan, YG Yang, GD Xing, Y Lin, YH Jia, HQ
Citation
Jq. Xu et al., Metal-oxo cluster-supported transition metal complexes: hydrothermal synthesis and characterization of [{M(phen)(2)}(2)(Mo8O26)] (M = Ni or Co), CHEM COMMUN, (11), 1999, pp. 983-984
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
1999
Pages
983 - 984
Database
ISI
SICI code
1359-7345(19990607):11<983:MCTMCH>2.0.ZU;2-G
Abstract
Two new metal-ore supported transition metal complexes, E{M(phen)(2)}(2)(Mo 8O26) (M = Ni or CO; phen = 1,10-phenanthroline) are synthesized by a hydro thermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)( 2)](2+) units are covalently bonded to the [Mo8O26](4-) cluster.