A novel two-dimensional honeycomb-like bimetallic iron(III)-nickel(II) cyanide-bridged magnetic material [Ni(cyclam)](3)[Fe(CN)(6)](2)center dot nH(2)O (cyclam=1,4,8,11-tetraazacyclodecane)

Authors
Colacio, E Dominguez-Vera, JM Ghazi, M Kivekas, R Lloret, F Moreno, JM Stoeckli-Evans, H
Citation
E. Colacio et al., A novel two-dimensional honeycomb-like bimetallic iron(III)-nickel(II) cyanide-bridged magnetic material [Ni(cyclam)](3)[Fe(CN)(6)](2)center dot nH(2)O (cyclam=1,4,8,11-tetraazacyclodecane), CHEM COMMUN, (11), 1999, pp. 987-988
Citations number
25
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
1999
Pages
987 - 988
Database
ISI
SICI code
1359-7345(19990607):11<987:ANTHBI>2.0.ZU;2-4
Abstract
The 2D honeycomb-like layered iron(III)-nickel(II) cyanide-bridged complex [Ni(cyclam)](3)[Fe(CN)(6)](2). nH(2)O exhibits ferromagnetic intralayer and antiferromagnetic interlayer interactions; above 3 K the magnetic properti es are typical of a metamagnet with H-c = 5000 G, whereas below 3 K a cante d structure is formed, leading to a long range ferromagnetic ordering.